Not possible, but
planned
I plan the dismemberment to be the best CS:S has seen. The system will allow for not only decapitation, but any other limbs as well.
You will be able to set how much HP (or what % of your original HP) until the dismemeberment occurs. You will be able to set what limb (usually head, but modelers can make other limbs and ZR would support it). You will be able to set the player's view to the decapitated head. For this it would be recommended that decap happens at low HP. Running around blind with 2000 HP isn't too fun, but having 300 HP to blindly run around would be funny and entertaining
Also I hope to get some gore gushing from the headless zombie.
Sound good?
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